The 2‐Arsaethynolate Anion: Synthesis and Reactivity Towards Heteroallenes
نویسندگان
چکیده
The synthesis and isolation of the 2-arsaethynolate anion, AsCO(-) , and its subsequent reactivity towards heteroallenes is reported. Reactions with ketenes and carbodiimides afford four-membered anionic heterocycles in formal [2+2] cycloaddition reactions. By contrast, reaction with an isocyanate yielded a 1,4,2-diazaarsolidine-3,5-dionide anion and the unprecedented cluster anions As10 (2-) and As12 (4-) . These preliminary reactivity studies hint at the enormous potential synthetic utility of this novel anion, which may be employed as an arsenide (As(-) ) source.
منابع مشابه
A Monoanionic Arsenide Source: Decarbonylation of the 2‐Arsaethynolate Anion upon Reaction with Bulky Stannylenes
We report fundamental studies on the reactivity of the 2-arsaethynolate anion (AsCO- ), a species that has only recently become synthetically accessible. The reaction of AsCO- with the bulky stannylene Ter2 Sn (Ter=2,6-bis[2,4,6-trimethylphenyl]phenyl) is described, which leads to the unexpected formation of a [Ter3 Sn2 As2 ]- cluster compound. On the reaction pathway to this cluster, several i...
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